资源类型

期刊论文 508

会议视频 10

年份

2023 51

2022 45

2021 61

2020 27

2019 32

2018 28

2017 28

2016 28

2015 25

2014 17

2013 20

2012 18

2011 14

2010 17

2009 17

2008 12

2007 19

2006 5

2005 6

2004 4

展开 ︾

关键词

制氢 4

可持续发展 3

中国 2

信息技术 2

农业科学 2

动物养殖 2

厌氧消化 2

发展趋势 2

可再生能源 2

多晶硅 2

智能制造 2

生产调度 2

1 1

5-戊二胺 1

cyp17a1 1

ANSYS二次开发 1

CMAQ模型 1

CO2利用 1

DNA组装 1

展开 ︾

检索范围：

排序： 展示方式：

PCDD/Fs emission, risk characterization, and reduction in China’s secondary copper production industry

Haiqian LI, Yonglong LU, Li LI

《环境科学与工程前沿（英文）》 2013年 第7卷 第4期   页码 589-597 doi: 10.1007/s11783-013-0495-2

摘要： Secondary copper production is one of the key polychlorinated dibenzo- -dioxins and dibenzofurans (PCDD/Fs) emission sources in China, but research and data on this issue are rare. In 2004, when the Stockholm Convention entered into force in China, PCDD/Fs emissions from secondary copper production contributed to 32.2% of the total release. In this paper, PCDD/Fs emission dynamics from secondary copper industry were discussed and cumulative risks were characterized. From 2004 to 2009, industrial policies played an indirect role in PCDD/Fs reduction, but its effects are still limited. The Yangtze River Delta, Pearl River Delta and central regions were among the top three of dioxin emissions from secondary copper production in China. Shanghai, Shandong, Zhejiang, and Jiangxi had comparatively higher accumulated risk and were recommended as the priority regions for promoting PCDD/Fs emission control in China. From 2009 to 2015, the PCDD/Fs emission dynamics in the secondary copper industry were presented through simulation. PCDD/Fs emission equations were established, resulting in the recommendation of control technology conversion rate at 30% for small scale smelters and 51%–57% for large and medium-sized enterprises in 2015. In conclusion, both indirect policy and direct control technology retrofitting should be integrated for more effective PCDD/Fs emission reduction in secondary copper industry.

关键词： polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs)     secondary copper production     emission     risk     China    

HTML PDF 收藏

Identification and assessment of environmental burdens of Chinese copper production from a life cycle

Xiaolong SONG,Jianxin YANG,Bin LU,Bo LI,Guangyuan ZENG

《环境科学与工程前沿（英文）》 2014年 第8卷 第4期   页码 580-588 doi: 10.1007/s11783-013-0599-8

摘要： The environmental burdens of Chinese copper production have been identified and quantified in the context of typical technologies, materials supplies and environmental emissions by a life cycle approach. Primary and secondary copper production using copper ores and scraps, respectively, were analyzed in detail. The flash and bath smelting approaches and the recycling of copper scraps were selected as representative copper production processes. A quantitative analysis was also conducted to assess the influence of material transport distance in copper production. Life cycle assessment (LCA) results showed that resources depletion and human health contribute significantly to environmental burdens in Chinese copper production. In addition, the secondary copper production has dramatically lower environmental burdens than the primary production. There is no obvious distinction in overall environmental burdens in primary copper production by flash or bath smelting approach. However, resources depletion is lower and the damage to human health is higher for flash smelting approach. Ecosystem quality damage is slight for both approaches. Environmental burdens from the mining stage contribute most in all life cycle stages in primary copper production. In secondary copper production, the electrolytic refining stage dominates. Based on the life cycle assessment results, some suggestions for improving environmental performance were proposed to meet the sustainable development of Chinese copper industry.

关键词： copper production     environmental burden     life cycle assessment     refined copper    

HTML PDF 收藏

Surface modification by ligand growth strategy for dense copper bismuth film as photocathode to enhancehydrogen production activity

《能源前沿（英文）》 doi: 10.1007/s11708-023-0893-5

摘要： Hydrogen production from photoelectrochemical (PEC) water splitting has been regarded as a promising way to utilize renewable and endless solar energy. However, semiconductor film grown on photoelectrode suffers from numerous challenges, leading to the poor PEC performance. Herein, a straightforward sol-gel method with the ligand-induced growth strategy was employed to obtain dense and homogeneous copper bismuthate photocathodes for PEC hydrogen evolution reaction. By various characterizations, it was found that the nucleation and surface growth of CuBi2O4 layer induced by 2-methoxyethanol ligand (2-CuBi2O4) demonstrated a decent crystallinity and coverage, as well as a large grain size and a low oxygen vacancy concentration, leading to the good ability of light absorption and carrier migration. Consequently, under simulated sunlight irradiation (AM1.5G, 100 mW/cm2), the 2-CuBi2O4 photocathode achieved an enhanced photocurrent density of −1.34 mA·cm−2 at 0.4 V versus the reversible hydrogen electrode and a promising applied bias photon-to-current efficiency of 0.586%. This surface modification by ligand growth strategy will shed light on the future design of advanced photoelectrodes for PEC water splitting.

关键词： copper bismuthate     photocathode     ligand growth strategy     dense film     PEC    

HTML PDF 收藏

Enhanced hydrogen production from aqueous methanol solution using TiO

Paramasivan GOMATHISANKAR,Tomoko NODA,Hideyuki KATSUMATA,Tohru SUZUKI,Satoshi KANECO

《化学科学与工程前沿（英文）》 2014年 第8卷 第2期   页码 197-202 doi: 10.1007/s11705-014-1417-y

摘要： The photocatalytic hydrogen production from aqueous methanol solution using titanium dioxide (TiO ) was investigated in the addition of metal particles including copper, lead, tin, and zinc. The results show that only the addition of copper particles enhances the hydrogen production. The copper usage and reaction temperature were further optimized for TiO /Cu photocatalyts. Under the optimal conditions, the hydrogen production using TiO /Cu as photocatalysts is approximately 68 times higher than that obtained with only TiO .

关键词： photocatalytic hydrogen generation     methanol     copper particles     TiO2     metal-semiconductor interface    

HTML PDF 收藏

闪速熔炼——清洁高效的炼铜工艺

周松林

《中国工程科学》 2001年 第3卷 第10期   页码 86-89

摘要：

闪速熔炼是当今铜冶金中最具有竞争力的熔炼技术，被认为是标准的清洁炼铜工艺。目前，全球粗铜产量的50%是采用该技术生产的。由于闪速熔炼符合可持续发展战略，世界上大部分新建或改扩建的铜企业均选择该工艺。文章就铜闪速熔炼的特点及发展，阐述了我国铜冶金的现状，提出了我国铜冶金的主要发展方向。

关键词： 闪速熔炼     铜冶金     环保     清洁生产    

HTML PDF 收藏

On secondary new particle formation in China

Markku Kulmala,Tuukka Petäjä,Veli-Matti Kerminen,Joni Kujansuu,Taina Ruuskanen,Aijun Ding,Wei Nie,Min Hu,Zhibin Wang,Zhijun Wu,Lin Wang,Douglas R. Worsnop

《环境科学与工程前沿（英文）》 2016年 第10卷 第5期 doi: 10.1007/s11783-016-0850-1

摘要： Formation of new atmospheric aerosol particles is a global phenomenon that has been observed to take place in even heavily-polluted environments. In China, new particle production has been observed at very high pollution levels (condensation sink about 0.1s ) in several megacities. A holistic scientific understanding on the atmospheric phenomena associated with air quality as a whole, as well as on the connection between air quality and climate, is lacking at the moment.With a network of observation stations, we will be able to understand the interactions and feedbacks associated with the urban pollution mixture, and ultimately, are ready to make targeted strategies for the pollution control. This paper summaries the recent advances in studying secondary new aerosol formation in China and shows how increased process-level understanding will help us to understand air quality-climate-weather interactions and how the feedbacks and interactions affect the air quality in highly-polluted environments such as those frequently encountered in Chinese megacities. Formation of new atmospheric aerosol particles is a global phenomenon that has been observed to take place in even heavily-polluted environments. However, in all environments there appears to be a threshold value of the condensation sink (due to pre-existing aerosol particles) after which the formation rate of 3 nm particles is no longer detected. In China, new particle production has been observed at very high pollution levels (condensation sink about 0.1 s ) in several megacities, including Beijing, Shanghai and Nanjing as well as in Pearl River Delta (PRD). Here we summarize the recent findings obtained from these studies and discuss the various implications these findings will have on future research and policy.

关键词： Aerosol particles     Heavily-polluted environments     Condensation sink     New particle production     Megacities    

HTML PDF 收藏

Copper and zinc interaction on water clearance and tissue metal distribution in the freshwater mussel

Tianxiang XIA, Xuehua LIU

《环境科学与工程前沿（英文）》 2011年 第5卷 第2期   页码 236-242 doi: 10.1007/s11783-010-0218-8

摘要： Copper and zinc interaction on clearance from water and distribution in different tissues was investigated for the freshwater mussel, , under laboratory conditions. Clearance rate of Cu or Zn from water was highly dependent on exposure concentration. Interaction effect was most evident at 300 μg·L Cu exposure and depressed the Zn clearance rate significantly ( <0.05). However, the presence of 100 μg·L and 300 μg·L Zn hardly affected the Cu clearance rate. The 300 μg·L Cu presence enhanced Cu accumulation in each tissue most significantly ( <0.01), but caused Zn content to decrease in the gills by 62% ( <0.05), viscera by 49% ( <0.05) and foot by 31% ( <0.05), and increase in the mantle by 97% ( <0.05) and the muscles by 243% ( <0.05) for different Zn exposure treatments. The response of metal accumulation in various tissues of the test mussels indicated that Zn transferred from the gills, viscera and foot to the mantle and muscles might be one of the important characteristics of the Zn regulatory mechanism by leading to a narrow range of Zn concentration in the different tissues.

关键词： interaction     mussel     copper     zinc     clearance     distribution    

HTML PDF 收藏

迎接铜工业挑战——低成本处理硫化铜精矿途径的思考

朱祖泽

《中国工程科学》 2000年 第2卷 第2期   页码 87-90

摘要：

对过去10年来铜冶炼的技术进步和铜价格的变化作出的简要回顾指出，未来铜市场的竞争是取决于冶炼技术的生产成本的竞争。坚持自我研究开发和引进相结合才能保证我国铜工业健康稳定发展，并能应付国际竞争。评述了现在强氧化-PS转炉吹炼-火法精炼-电解流程的不足；分析了火湿法联合流程的可能性及依据；新的火湿法联合流程将有更强的竞争优势。

关键词： 未来铜工业     硫化铜精矿     低成本处理    

HTML PDF 收藏

Mechanisms for simultaneous ozonation of sulfamethoxazole and natural organic matters in secondary effluent

《环境科学与工程前沿（英文）》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1368-0

摘要：

• SMX was mainly degraded by hydrolysis, isoxazole oxidation and double-bond addition.

关键词： Sulfamethoxazole     Ozonation     Natural organic matters     Secondary effluent     Degradation mechanism    

HTML PDF 收藏

Variability of waste copper slag concrete and its effect on the seismic safety of reinforced concrete

《结构与土木工程前沿（英文）》 2022年 第16卷 第1期   页码 117-130 doi: 10.1007/s11709-021-0788-7

摘要： Proven research output on the behavior of structures made of waste copper slag concrete can improve its utilization in the construction industry and thereby help to develop a sustainable built environment. Although numerous studies on waste copper slag concrete can be found in the published literature, no research has focused on the structural application of this type of concrete. In particular, the variability in the strength properties of waste copper slag concrete, which is required for various structural applications, such as limit state design formulation, reliability-based structural analysis, etc., has so far not attracted the attention of researchers. This paper quantifies the uncertainty associated with the compressive-, flexural- and split tensile strength of hardened concrete with different dosages of waste copper slag as fine aggregate. Best-fit probability distribution models are proposed based on statistical analyses of strength data generated from laboratory experiments. In addition, the paper presents a reliability-based seismic risk assessment of a typical waste copper slag incorporated reinforced concrete framed building, considering the proposed distribution model. The results show that waste copper slag can be safely used for seismic resistant structures as it results in an identical probability of failure and dispersion in the drift demand when compared with a conventional concrete building made of natural sand.

关键词： waste copper slag     quantification of variability     goodness-of-fit test     seismic risk assessment     PSDM    

HTML PDF 收藏

Physical and chemical processes of wintertime secondary nitrate aerosol formation

Qi YING

《环境科学与工程前沿（英文）》 2011年 第5卷 第3期   页码 348-361 doi: 10.1007/s11783-011-0343-1

摘要： The UCD/CIT model was modified to include a process analysis (PA) scheme for gas and particulate matter (PM) to study the formation of secondary nitrate aerosol during a stagnant wintertime air pollution episode during the California Regional PM /PM Air Quality Study (CRPAQS) where detailed measurements of PM components are available at a few sites. Secondary nitrate is formed in the urban areas from near the ground to a few hundred meters above the surface during the day with a maximum modeled net increase rate of 4 μg·m ·d during the study episode. The secondary nitrate formation rate in rural areas is lower due to lower NO . In the afternoon hours, near-surface temperature can be high enough to evaporate the particulate nitrate. In the nighttime hours, both the gas phase N O reactions with water vapor and the N O heterogeneous reactions with particle-bound water are important for secondary nitrate formation. The N O reactions are most import near the surface to a few hundred meters above surface with a maximum modeled net secondary nitrate increase rate of 1 μg·m ·d and are more significant in the rural areas where the O concentrations are high at night. In general, vertical transport during the day moves the nitrate formed near the surface to higher elevations. During the stagnant days, process analysis indicates that the nitrate concentration in the upper air builds up and leads to a net downward flux of nitrate through vertical diffusion and a rapid increase of surface nitrate concentration.

关键词： secondary nitrate aerosol     N2O5 heterogeneous reaction     process analysis    

HTML PDF 收藏

Microwave enhanced stabilization of copper in artificially contaminated soil

Hua ZHANG, Zhiliang ZHU, Noboru YOSHIKAWA

《环境科学与工程前沿（英文）》 2011年 第5卷 第2期   页码 205-211 doi: 10.1007/s11783-010-0290-2

摘要： Microwave processing was used to stabilize copper ions in soil samples. Its effects on the stabilization efficiency were studied as a function of additive, microwave power, process time, and reaction atmosphere. The stabilization efficiency of the microwave process was evaluated based on the results of the toxicity characteristic leaching procedure (TCLP) test. The results showed that the optimal experimental condition contained a 700 W microwave power, 20 min process time and 3 iron wires as the additive, and that the highest stabilization efficiency level was more than 70%. In addition, the different reaction atmospheres showed no apparent effect on the stabilization efficiency of copper in the artificially contaminated soil. According to the result of the Tessier sequential extraction, the partial species of copper in the contaminated soil was deduced to transform from unstable species to stable states after the microwave process.

关键词： microwave     copper     stabilization    

HTML PDF 收藏

Cuprous oxide/copper oxide interpenetrated into ordered mesoporous cellulose-based carbon aerogels for

《化学科学与工程前沿（英文）》 2023年 第17卷 第7期   页码 918-929 doi: 10.1007/s11705-023-2305-0

摘要： The casual discharge of dyes from industrial settings has seriously polluted global water systems. Owing to the abundance of biomass resources, preparing photocatalysts for photocatalytic degradation of dyes is significant; however, it still remains challenging. In this work, a cuprous oxide/copper oxide composite was interpenetrated onto carbon nanosheets of cellulose-based flexible carbon aerogels (Cu2O/CuO@CAx) via a simple freeze-drying-calcination method. The introduction of the carbon aerogel effectively prevents the aggregation of the cuprous oxide/copper oxide composite. In addition, Cu2O/CuO@CA0.2 has a larger specific surface area, stronger charge transfer capacity, and lower recombination rate of photogenerated carriers than copper oxide. Moreover, Cu2O/CuO@CA0.2 exhibited high photocatalytic activity in decomposing methylene blue, with a degradation rate reaching up to 99.09% in 60 min. The active oxidation species in the photocatalytic degradation process were systematically investigated by electron spin resonance characterization and poisoning experiments, among which singlet oxygen played a major role. In conclusion, this work provides an effective method for preparing photocatalysts using biomass resources in combination with different metal oxides. It also promotes the development of photocatalytic degradation of dyes.

关键词： carbon aerogel     photocatalysis     dye degradation     biomass     cuprous oxide/copper oxide    

HTML PDF 收藏

Two-echelon Emergency Response Problem and Simulation Considering Secondary Disasters

Han-peng Zhang,Yi Liao,Hui-xia Luo

《工程管理前沿（英文）》 2014年 第1卷 第3期   页码 318-321 doi: 10.15302/J-FEM-2014042

摘要： It is necessary for subsequent resource distribution planning that get expected relief time considering secondary disasters after natural disaster. The goal of this research is to develop a two-echelon emergency resource distribution model under condition of secondary disasters. Taking minimal maximize relief time as criterion of relief performance, we developed response strategies and simulation model to get the expected value. Numerical studies of this paper presented the result of response strategies.

关键词： simulation     secondary disasters     two-echelon vehicle routing model    

HTML PDF 收藏

Formation of secondary inorganic aerosol in a frigid urban atmosphere

《环境科学与工程前沿（英文）》 2022年 第16卷 第2期 doi: 10.1007/s11783-021-1452-0

摘要：

•Harbin showed relatively high threshold RH (80%) for apparent increase of SOR.

关键词： Haze     Sulfate     Nitrate     Heterogeneous chemistry     Biomass burning     Northeast China    

HTML PDF 收藏

标题 作者 时间 类型 操作

PCDD/Fs emission, risk characterization, and reduction in China’s secondary copper production industry

Haiqian LI, Yonglong LU, Li LI

期刊论文

Identification and assessment of environmental burdens of Chinese copper production from a life cycle

Xiaolong SONG,Jianxin YANG,Bin LU,Bo LI,Guangyuan ZENG

期刊论文

Surface modification by ligand growth strategy for dense copper bismuth film as photocathode to enhancehydrogen production activity

期刊论文

Enhanced hydrogen production from aqueous methanol solution using TiO

Paramasivan GOMATHISANKAR,Tomoko NODA,Hideyuki KATSUMATA,Tohru SUZUKI,Satoshi KANECO

期刊论文

闪速熔炼——清洁高效的炼铜工艺

周松林

期刊论文

On secondary new particle formation in China

Markku Kulmala,Tuukka Petäjä,Veli-Matti Kerminen,Joni Kujansuu,Taina Ruuskanen,Aijun Ding,Wei Nie,Min Hu,Zhibin Wang,Zhijun Wu,Lin Wang,Douglas R. Worsnop

期刊论文

Copper and zinc interaction on water clearance and tissue metal distribution in the freshwater mussel

Tianxiang XIA, Xuehua LIU

期刊论文

迎接铜工业挑战——低成本处理硫化铜精矿途径的思考

朱祖泽

期刊论文

Mechanisms for simultaneous ozonation of sulfamethoxazole and natural organic matters in secondary effluent

期刊论文

Variability of waste copper slag concrete and its effect on the seismic safety of reinforced concrete

期刊论文

Physical and chemical processes of wintertime secondary nitrate aerosol formation

Qi YING

期刊论文

Microwave enhanced stabilization of copper in artificially contaminated soil

Hua ZHANG, Zhiliang ZHU, Noboru YOSHIKAWA

期刊论文

Cuprous oxide/copper oxide interpenetrated into ordered mesoporous cellulose-based carbon aerogels for

期刊论文

Two-echelon Emergency Response Problem and Simulation Considering Secondary Disasters

Han-peng Zhang,Yi Liao,Hui-xia Luo

期刊论文

Formation of secondary inorganic aerosol in a frigid urban atmosphere

期刊论文